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ESD PEEK Rods

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ESD PEEK RODS
What is an ESD PEEK ROD?
 
ESD PEEK ROD (anti-static polyetheretherketone rod) is a solid cylindrical polymer material based on polyetheretherketone (PEEK) resin, modified to impart electrostatic discharge (ESD) protection. Its key feature is that while retaining the inherent high performance of PEEK (high temperature resistance, chemical corrosion resistance, and high mechanical strength), the rod is enhanced with controllable conductivity (surface/volume resistivity typically ranging from 10⁶ to 10⁻¹⁻Ω) through the addition of conductive fillers or surface treatment. This allows for the slow or rapid dissipation of static electricity, preventing damage to sensitive environments or components caused by static buildup.
 
 
ESD PEEK ROD Formation Process
The preparation process for ESD PEEK RODs is similar to that for ESD PEEK sheets. However, because the rods must maintain a consistent aspect ratio (typically reaching lengths of several meters, with diameters ranging from 3 to 200 mm) and high dimensional accuracy, the molding process requires more stringent control. This process is primarily divided into three stages:
 
1. Raw Resin Synthesis
PEEK resin is prepared via nucleophilic substitution polymerization: 4,4'-difluorobenzophenone (DFBP) and hydroquinone (HQ) are used as monomers. Polycondensation occurs in a polar aprotic solvent at 280-320°C under high pressure (approximately 3-4 MPa) to produce a high molecular weight PEEK polymer (typically 30,000-60,000 g/mol).
 
2. Modification and Compounding
To impart ESD functionality, PEEK resins require the addition of conductive fillers (the most common method) or surface coating (less commonly used for rods).
 
Filler-Based Modification (Mainstream): Select a conductive filler with good compatibility with PEEK (such as carbon black, carbon nanotubes, metal powder, conductive fiber, etc.) and mix it with the PEEK resin in a suitable proportion (5%-20%). High-speed stirring, an internal mixer, or a twin-screw extruder are required to uniformly disperse the filler and form a continuous conductive network (to avoid localized high resistance).
 
Carbon black: Low cost, but may affect transparency;
Carbon nanotubes: High conductivity (low dosage), but difficult to disperse;
Metal powder: Excellent conductivity (close to metal), but high density and prone to oxidation;
Carbon fiber: Combines conductivity with enhanced mechanical properties (tensile strength can be increased by 10%-20%).
 
3. Molding (Core Difference: Extrusion Process Requires Precise Control)
The modified PEEK composite material is extruded into rods. Controlling the temperature, pressure, and cooling rate during the extrusion process is crucial to ensure the rod's roundness, straightness, and internal crystallization uniformity.
 
Equipment Selection: Use a twin-screw extruder with a high aspect ratio (L/D) (L/D = 36-48) and a specially designed extrusion die (such as a split-flow die) to ensure uniform melt distribution within the die.
 
ESD PEEK RODS BLACK
 
Features and Advantages of ESD PEEK Rod
 
Electrical Properties
Controllable surface resistivity (SR) or volume resistivity (VR) (10⁶ to 10⁹Ω), short static dissipation time (typically <1 second).
 
Mechanical Properties
High tensile strength (≥70 MPa), fatigue resistance (long life under cyclic loading), near-metallic density at only 1.46 g/cm³ (lightweight).
 
High Temperature Resistance
Long-term operating temperature 250°C (short-term operating temperature up to 310°C), melting point (Tm) 343°C.
 
Chemical Resistance
Resistant to most organic solvents (such as alcohols and hydrocarbons), concentrated acids and bases (except concentrated sulfuric acid and nitric acid), and hydrolysis resistance (can withstand long-term use in high-temperature, high-pressure steam).
 
Radiation Resistance
Strong resistance to gamma rays and X-rays (maintains performance up to 10⁹ Gy), suitable for the nuclear industry.
 
Biocompatibility
Non-toxic, non-sensitizing, and sterilizable (resistant to autoclave sterilization at 134°C).
 
Dimensional Stability
Low hygroscopicity (water absorption <0.1% at 23°C/50% RH), low thermal expansion coefficient, and high dimensional accuracy during processing.
 
ESD PEEK RODS 30MM
 
Advantages over other materials:
 
Compared to standard PEEK rods: Added ESD protection prevents static electricity from damaging electronic components and precision instruments.
 
Compared to metal rods: Lower density, greater corrosion resistance, no metal ion precipitation, and easy processing.
 
Compared to conductive plastic rods: Significantly superior temperature resistance (>250°C), aging resistance (UV resistance), and long-term mechanical strength, making it suitable for high-temperature, high-corrosion environments (such as semiconductor equipment).
 
ESD PEEK SHEET AND ROD
AHD ESD PEEK Sheet and Rod
 
Considerations for Specific Applications
 
1. Processing and Molding
 
Filler Dispersion Control: Filled ESD PEEK rods require uniform dispersion of the conductive filler (otherwise, localized resistance will be excessively high, leading to static electricity accumulation). It is recommended to use a twin-screw extruder and optimize the screw configuration (such as adding shear elements), or adopt a "masterbatch method" (premixing the filler with PEEK into a masterbatch before extrusion).
 
Extrusion Process Stability: Extrusion temperature and pulling speed must be strictly controlled to avoid uneven internal stress in the rod (manifested as surface ripples or internal cracks) caused by temperature or speed fluctuations.
 
Post-Processing: Extruded rods require annealing (150-200°C for 2-4 hours) to eliminate internal stress and improve dimensional stability.
 
2. Storage and Environment
 
Moisture and Dust Control: Although PEEK has low hygroscopicity, the rod has a large surface area. Prolonged exposure to high humidity or dusty environments may cause surface condensation or adsorption of impurities, which may affect ESD performance or subsequent processing. It is recommended to store in a dry, clean warehouse, sealed with moisture-proof bags and dust-proof film.
 
Avoid mechanical damage: The rods are highly rigid, but sharp impacts may cause surface scratches (damaging the conductive network). Use a soft protective sheath during transportation and store upright to avoid bending and deformation.
 
3. Usage and Maintenance
 
Load Limits: When used as structural components, the load should be calculated based on the rod's mechanical properties (such as tensile strength and flexural modulus) (a safety factor of ≥ 2 is recommended).
 
Temperature and Chemical Compatibility: Long-term operating temperatures should not exceed 250°C, and short-term peak temperatures should not exceed 300°C (exceeding this temperature may cause failure of the filler-matrix interface). Avoid contact with strong oxidizers or highly polar solvents to prevent swelling or degradation.
 
Surface Maintenance: If the surface is scratched, promptly polish and repair it to prevent scratch extension. However, retest the surface resistivity after polishing to ensure it still meets ESD standards.
 
4. Design and Compliance
 
ESD Standard Compatibility: Select the appropriate resistivity based on the application scenario.
 
Welding and Bonding: If bonding to other materials (such as metals) is required, it is recommended to use a specialized adhesive (such as epoxy adhesive compatible with PEEK) or induction welding to avoid fillers that may affect weld strength.
 
 
ESD PEEK ROD is a typical material that combines high-performance engineering plastics with ESD protection. Its high-temperature and chemical resistance, high mechanical strength, and controllable conductivity make it an irreplaceable structural or functional component in high-end manufacturing fields such as semiconductor equipment, medical devices, and aerospace. During use, it is important to control the processing technology (such as extrusion parameters and annealing treatment), environmental storage conditions (moisture and dust protection), and load limits to ensure its ESD protection performance and long-term reliability.
 
ESD PEEK BARS BLACK
 
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